Absorption Chilling


There is growing interest in a method of cooling buildings which uses gas as a fuel instead of electricity. The technology is known as absorption cooling. The biggest differences between this and vapour compression cooling are that the compressor is replaced by a gas fired generator and the refrigerant is replaced by a refrigerant/ absorber mixture. A diagram of an absorption chiller is shown in below figure. The generator is filled with a mixture of refrigerant and absorber (solvent) which can be either water/lithium bromide (>35kW capacity) or ammonia/water. (>11kW). Note because water freezes the lithium bromide/water units can only cool down to 5oC, ammonia/water units on the other hand can cool down to -10oC. The way the system works can be illustrated using the ammonia/water pairing as an example. In this case water is the absorber and ammonia is the refrigerant. The water is called the absorber, giving the process its name, as it is so chemically attracted to ammonia vapour that it absorbs it out of the atmosphere.


A concentrated solution of ammonia in water is heated in the generator (figure 5.4) using a gas burner. The ammonia component vaporizes first, as it has a lower boiling point than water, and passes into the condenser. The water which is left behind passes back to the absorber. The ammonia vapour condenses back to liquid ammonia in the condenser giving out waste heat. This heat is removed from the system by air which is blown over the condenser by a fan. The ammonia now passes from the condenser into the evaporator via an expansion valve. In doing so its pressure drops and so it can evaporate once more. It does this by absorbing heat from the chilled water circuit. Chilling has therefore, been achieved.
The ammonia vapour now passes into the absorber where it is absorbed by the water from the generator to create a concentrated ammonia solution. Heat is given out when the two chemicals combine. This waste heat is also removed by the condenser cooling air flow. The ammonia solution is pumped back to the generator where the cycle continues once more.

The above device is known as a single effect absorption chiller. Double effect units are also available which use water and lithium bromide. This solution is pre heated on its way back to the generator by passing it through a heat exchanger. This improves the efficiency of the unit. Double effect units require a higher temperature heat source (>140oC) derived from a direct gas fired burner or pressurised hot water.

Absorption chillers are less efficient than vapour compression chillers with a COP of approximately 0.7-1.2. It follows that more gas energy will be required than an equivalent electric chiller (COP = 3.0). However the cost and pollution differentials will be reduced because electricity costs and pollutes approximately four times more per unit of energy than gas because of wastage in the power stations. Contract gas prices are lower still in summer when gas is needed for cooling as less is needed for space heating.

As well as direct gas firing some absorption chillers can be operated using waste heat. One form of surplus heat is that generated by combined heat and power units. In winter their heat output is used for space heating. In summer this heat is surplus to requirements and so can be used to drive the absorption chiller. This is known as trigeneration or combined cooling and power. When heat, which would normally be wasted, is used absorption chillers emit much less CO2 into the atmosphere than a vapour compression chiller for a given cooling effect. Research is currently underway which is investigating the linking of absorption chillers with solar panels as a source of generator heat. It is an advantage that the appearance of large amounts of cost and pollution free solar energy coincides with the need for cooling.


Other Benefits

The only electrical elements in an absorption chiller are the pumps used to move the ammonia/water solution from the absorber back to the generator. These pumps consume much less power and produce less noise and vibration than a compressor. This latter point is useful if the chiller is to be sited near to a noise sensitive area.

The pump along with the air cooled condenser fan and the gas burner fan are the only moving parts. The rest of the device consists of sealed metal chambers. This configuration means that maintenance costs are low.

External, air cooled, modular packaged units mean that cooling capacity can be easily expanded as the building is developed or as heat loads increase. Flexibility is further enhanced as units are also available that provide heating in winter and switch to cooling in summer.



Selection Criteria

From the above it can be seen that absorption chilling is particularly appropriate where:

· You have excess heat production from your CHP plant in summer or a production process which can be used to drive the absorption chiller

· The electrical supply to the site is not robust enough to supply the necessary electricity required for vapour compression chilling and an expensive upgrade would be necessary.

· You wish to optimize the use of clean gas as a fuel throughout the year, not just in winter.

· You have a source of low cost or free heat energy available such as solar energy or heat released from the combustion of landfill gas.